Get notified on Chat/mail arrives with Gmail desktop notifier
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To turn Gmail desktop notifier on your Gmail account, you need to click on Settings link on your Gmail account at the top right corner.There you will have to choose if you are wishing to get notified on new message/mail only or you can turn on Chat notification from Gmail as shown in image here and save.
See also : Cheaper voice calling from Gmail | Backup your Emails in to a Pen Drive
HTML5-based and currently works only in Chrome only, but Google mail blog says they are currently working on to make those notification as a part of the standard Web platform.
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